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13.- 1x07 "Haunted"
14.- 1x04 "Family Ties"
15.- 1x06 "Lost Girls"
16.- 1x12 "Unpleasantville"
17.- 1x08 "162 Candles"
18.- 1x09 "History Repeating"
19.- 1x16 "There Goes The Neighborhood"
20.- 1x01 "Pilot"

Episode 1.02 – The Night of the Comet: Elena and Damon meet for the first time at the Salvatore house and his revelation about Stefan's past brings Elena closer to the truth.

Episode 1.03 – Friday Night Bites: During dinner, Damon and Caroline unexpectedly show up, and Elena "invites" him into her house.

Episode 1.11 – Bloodlines: Damon's arrival causes the mysterious stranger to flee, and Damon frees Elena from her overturned car. Damon brings Elena with him to Georgia to see Bree, a witch and an old flame of Damon's, hoping she can help open the tomb to free Katherine. Bree calls Lee, Lexi's boyfriend (as Lexi was her friend), who wants revenge on Damon. Elena saves Damon, and he kills Bree after she tells him to find Emily's spellbook.

Episode 1.13 – Children of the Damned: Damon interrupts Elena and Stefan in bed. Damon reminds them he can be trusted then leaves. Elena helps Stefan as he and Damon race to find the missing journal that belonged to Elena’s ancestor. Damon finds Elena and Stefan there after they dig the Grimoire up from his father's grave. Damon takes the book.

Episode 1.14 – Fool me Once: With the help of Bonnie and Grams, the tomb is opened and Damon realizes that Katherine is not inside. Stefan warns Damon that the seal of the tomb has only been temporarily broken, and Elena helps them both escape in order to not be sealed in forever. Out of the tomb, Elena sees how upset Damon is and comforts him.

Episode 1.15 – A Few Good Men: Elena helps Damon get dressed. Elena finds out that Damon “killed” her mother. Damon get the clue from Elena he may have killed her mom, Isobel.

Episode 1.17 – Let The Right One In: At the Salvatore’s mansion, Damon and Elena argue about Pearl. Damon contacts Elena and they both realize that Stefan is in trouble. Damon and Elena under the rain. Damon doesn’t want Elena involved in the rescue. Elena decides to make her way into the house and Damon has to save her.

Episode 1.18 – Under Control: She asks, he comes. It’s easy like that. Damon and Elena chat at the party about Stefan and Jeremy.

Episode 1.19 – Miss Mystic Falls: Damon explains to Elena that Stefan is in bad shape and can screw up everything if he doesn’t get his blood lust under control. Elena is finally called, but since Stefan is nowhere to be found, Damon steps in and they begin the introduction dance. Damon and Elena lock Stefan in the cage in the basement.

Episode 1.20 – Blood Brothers: As Stefan tries to come to terms with his past, he and Damon reveal pieces of their history to Elena, including the truth about how they were turned into vampires. Stefan and Elena return to the house and Stefan seems to be cured of the blood-craze but Damon doesn't seem happy about it.

Episode 1.21 – Isobel: Damon and Elena talk on the phone. Alaric tells the brothers and Elena that her mother wants to know her. Damon tackles Isobel to the floor and tries to throttle her. Elena tries to convince Damon to give her the device. Isobel knows better: “‘Cause he’s in love with you.”.

Episode 1.22 – Founder’s Day: Damon jumps in front of Bonnie and waves to Elena. Elena tells Damon that Stefan is worried about her friendship with him. Damon tells Elena how he feels about her and they kiss but the girl is not Elena but Katherine

I don't know :( I love them all ¬¬

Good Delena moments, but the others have better scenes. A Few Good Men was the the first episode where Damon showed remorse for ANYTHING, and it was because of Elena. That was a really strong DE scene for me.

Also "She left you. She sucks"

or 1x15,i think. i couldn`t choose their first meeting. it means too much to me.

this one didn't really have any good scenes...that are worth mentioning....or night of the comet..

It's really hard to pick now though because I love them all. However I'm going to pick this episode as I love the rest more. I don't get why people wouldn't like the second episode for Delena though because it was their first meeting and because of this, after future seasons we can look back to their first meeting and see how much they have changed.

i liked all but i just picked one